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如第 6 章所述，光诱导的电子转移可以分为两种情况：电子供体的激发和电子受体的激发，表示为 D*+A → D+•+A−• → D+A+hν（D 将激发态电子转移到 A 的 LUMO，接着电子从 A 的 LUMO 回到 D 的基态轨道而发光）和 D+A* —→ D+•+A−• → D+A+hν（A 被激发后，D 将 HOMO 电子转移到 A 的 HOMO 或空穴，接着处于 A 激发态电子跃迁至 D 的 HOMO 而发光）。
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